Thermoplastic polyester
2-8 usd/kgThermoplastic polyester offers an amazing balance of properties considering its very low price. As a result, it dominates in textiles, films and engineering. The most important of this group is polyethylene terephthalate (PET, PETE) – a low cost plastic available in many formats and commercially significant in many industries. While they have moderate mechanical properties, they have some in-built resistance to weathering, chemicals and fire; which can be enhanced. As a packaging material polyester provides a barrier against water, CO2, oxygen and nitrogen – perhaps the most iconic use of this material is in plastic drinks bottles.
At high temperatures polyester is very sensitive to moisture and particularly vulnerable to water at over 60 degC. Copolyesters have been developed to overcome this shortfall and grades are available that are able to be utilised in reusable, transparent, dishwashable food and drink containers, for example. On the other hand, in the case of biodegradable plastics, this weakness may be enhanced to enable composting end of life. When combined with raw materials from biological sources, it is possible to make bio-based biodegradable polyesters that meet the most stringent composting requirements and are suitable for a range of packaging, textile and industrial applications.
Polyester may be partially, or wholly, derived from biomaterials. Certain types, such as polytrimethylene terephthalate (PTT), have biomaterial derived ingredients as part of their fundamental chemistry, which may or may not be advantageous, depending on the source of the material. Polyethylene furanoate (PEF) is 100% bio-based and offers a superior material to PET in many applications. These materials are not biodegradable.
Log in to search similar materials
Log in to find better material
Sustainability concerns
Polyethylene furanoate (PEF) is a 100% bio-based polyester that is recyclable, but not biodegradable. Compared to polyethylene terephthalate (PET), it offers superior strength, barrier and thermal properties. It is suitable for a range of packaging applications, similar to PET, such as containers, pouches and films.
Its superior barrier properties, compared to PET, make it suitable for single layer carbonated soft drinks bottles. PET often requires a barrier layer, such as polyamide (PA), nylon, formed as a multi-layer structure. This creates problems for recycling, because anymore than around 5% nylon and the polyester becomes hazy in appearance and unsuitable for transparent applications. PEF can be used in place of nylon to provide a barrier layer. While it also affects recycling, polyester can tolerate a higher percentage before the haziness if affected too much.
Compared to PET, it has a slightly higher thermal resistance. While still not able to tolerate 100 degC, it retains its mechanical properties up to around 80 degC.
PEF fibres are suitable for textiles used in medical, healthcare, fashion, interior, carpets and upholstery.
Bio-based PEF has only recently become commercially available, in part due to the challenge of manufacturing one of its key ingredients at scale from bio-based ingredients: FDCA (furandicarboxylic acid) monomer. Avantium constructed the world’s first commercial facility for FDCA in the Netherlands in 2024.

