Silica
7-20 usd/kgSilica is an abundant mineral – sand is a form of silica, although it often contains many impurities. It is an important industrial material and a key ingredient in building materials (concrete and bricks), manufacturing (food and pharmaceutical processing) and high-performance glass (fused silica and quartz). The difference between silica and quartz, is that quartz is made up of naturally occurring crystalline mineral, which is primarily silica, but with the addition of a very small amount of impurity.
Silica is inert to most chemicals (except hydrofluoric acid and phosphoric acid), an electrical insulator, incredibly resistant to thermal shock and very stable at high temperatures, and has extensive optical transmission properties, from ultra violet through (80%) visible (93%) and infra red spectrums. These attributes are utilised in laboratory equipment (lenses and crucibles for example), manufacturing (food and pharmaceutical, for example), lenses and lamps for sensing and imaging, and parts for radiation environment equipment.
Producing shaped parts from silica and quartz is challenging, due to the high melting point (it begins to soften at 1,630 degC), and is limited to glass blowing and machine cutting. Lenses are cut and ground from quartz blocks to a precise finish using diamond tools, for example.
Fine silica dust (such as produced by abrading and machining) is a known health risk and too much exposure can be hazardous. Regulations are in place in many countries and regions to reduce the risk of exposure.
Sustainability concerns
Known as fused silica, fused quartz, quartz glass and quartz crystal, it is produced by melting quartz grains or a chemical precursor at very high temperature to produce an amorphous ‘glassy’ solid.
Type I – quartz sand is melted by electric fusion (c. 2000 degC) in an inert atmosphere.
Type II – natural quartz is used as the started material and melted with a high-temperature oxygen-hydrogen flame.
Type III – a synthetic precursor (silicon tetrachloride, SiCl4) is melted with an oxygen-hydrogen flame, to create SiO4.
Type IV – in this case plasma is used as the heat source, creating a pure and stable material from SiCl4 precursor.
Impurities affect transmission efficiency in the finished material. Typically transparent, impurities and air bubble inclusion can cause the material to become translucent.
The theoretical properties of fused silica are superseded by the design limits, because the strength of the material is governed more by surface imperfections and impurities, than what it can achieve based on it’s chemistry – strength depends on quality.

