Polystyrene (PS)

0.7-1.6 usd/kg
Circularity potential
Medium
Strength
Medium
Production energy
Very high
Stiffness
Low
Embodied CO2
Medium
Density
Medium

Polystyrene (PS) is a cheap plastic used for moulded packaging and disposables, as well as a rigid foam, expanded PS (EPS). Both have their own unique set of qualities but may still be useful for the same applications, but for different reasons. For example, food containers – one thin and transparent, and the other an insulating and protective foam. While the monomer styrene is extremely hazardous and a known carcinogen, it is considered non-hazardous once polymerised. However, there may be instances where the monomer is not fully polymerised and can potentially leach out, such as into lipophilic food.

As a moulded plastic it has excellent transparency and resistance to water. It is predominately used in packaging and medical containers, as well as brightly coloured tableware and disposables. PS is brittle and will breakdown relatively quickly when exposed to sunlight, becoming yellow. Where transparency and durability are required, there are many alternative options available depending on the requirements, such as polycarbonate (PC), polymethyl methacrylate (PMMA), acrylic and polyethylene terephthalate (PET), polyester. Plastic free options include soda lime glass and borosilicate glass.

Expanded polystyrene (EPS) is a lightweight and rigid foam that provides excellent impact absorption and insulating properties. These qualities are utilised for packaging, safety and as a construction material. It provides an important role as insulation, saving energy throughout its life. However, it is quite voluminous and this presents some challenges with transportation and recycling. Only a very small percentage is PS (typically 2-5%), which means it may be considered too expensive or impractical to collect and recycle.


Sustainability concerns
Non-renewable ingredients
Raw material generates polluting by-products
Microplastics


General purpose polystyrene (PS or GPPS) is utilised for its very low cost, water-clear transparency and relatively hard surface (compared to other commodity polymers). It has reasonably good dimensional stability, is suitable for food contact and has very good moulding properties. It can be injection moulded and thermoformed at high speed into thin-walled parts with good dimensional accuracy. This combination of properties makes it particularly well-suited to the food service industry for inexpensive mass-produced trays, containers, utensils, plates and bowls. Its poor durability means it tends to only be used for throw-away items – not particularly sustainable if they are not being recycled.

It resistance to water, excellent moulding properties and dielectric properties are utilised in electrical components and appliances, ranging from small connectors and antennas to large white goods such as linings for refrigerators and freezers.


Design properties
Cost usd/kg
1-1.3
Embodied energy MJ/kg
74-149
Carbon footprint kgCO2e/kg
2.5-4.4
Density kg/m3
1045
Tensile modulus GPa
3-3.6
Tensile strength MPa
30-44
Flexural modulus GPa
3.2
Flexural strength MPa
76
Compressive strength MPa
90
Hardness Mohs
1.5
Rockwell hardness R-scale
85-90 D
Poissons ratio
0.4
Thermal expansion (µm/m)/ºC
98-120
Heat deflection temperature ºC
90
Thermal conductivity W/mK
0.1-0.14
Temperature min-max °C
-20 to 60
Thermal
insulator
Electrical
insulator