Circularity potential
Medium
Strength
Medium
Production energy
High
Stiffness
Low
Embodied CO2
Medium
Density
Low

A lightweight, low cost, widely recycled commodity plastic useful in packaging, textiles, automotive and household goods – it is one of the most widely used plastics. It is impermeable to water, highly resistant to chemicals, very durable, insulating and resistant to fatigue. The homopolymer is available in biocompatible grades suitable for healthcare applications.

PP is one of the least expensive polymers and available in many different grades and formats. Whereas low-grade recycled material can offer cost savings versus virgin, recycled grades of high quality (light colours, no odour and so on) can add up to 50% to the base price. Bio-based materials are up to twice the price, depending on the source and feedstock, but this is likely to come down with time and developments in the technology.

Due to it’s semi-crystalline structure, it has a naturally milky appearance. However, types (such as random copolymer) and additives (clarifiers) have been developed to produce a more transparent appearance in the finished article. Clarifiers are suitable for food application (microwave, dishwasher, freezer and hot-fill safe) and produce a clear, colour-free material. This brings PP into competition with amorphous materials, such as polycarbonate (PC) and even glass, for containers and packaging.

It is combined with various fillers – including mineral (talc), glass fibre, carbon fibre and natural materials (such as wood, hemp and bamboo) – to improve mechanical properties and, in the case of wood-fill, reduce cost and weight. Maleic anhydride grafted polypropylene (PP-g-MAH) is commonly used as the base material, because it improves coupling between the polymer and filler material.

It has low surface energy, which is useful in many cases, but also means it is difficult, but not impossible, to bond with adhesive. It will burn readily when exposed to an open flame (UL 94 HB). It is possible to add flame retardant additives to achieve UL 94 V0, but this has an impact on mechanical properties.


Sustainability concerns
Microplastics


Bio-based polypropylene (bio-PP) provides a renewably sourced alternative to petroleum PP. It is suitable as a drop-in replacement, but the relatively higher price means it has not been so widely adopted. PP is the second most consumed plastic, after polyethylene (PE), and used for predominantly price-sensitive applications.

Bio-PP is not biodegradable, but it is suitable for recycling. The carbon footprint of bio-PP is low when using waste oil as the feedstock. For example, naphtha is a petrochemical feedstock used in the production of plastics, such as PP. Traditionally derived from crude oil and natural gas, it can now be produced from renewable feedstock, such as used cooking oil and crude tall oil, a residue of paper pulp production.


Design properties
Cost usd/kg
2-4
Embodied energy MJ/kg
53.4-57
Carbon footprint kgCO2e/kg
0.5-0.8
Density kg/m3
905
Tensile modulus GPa
1.5-1.8
Tensile strength MPa
35-40
Flexural modulus GPa
1.3-2.15
Flexural strength MPa
34
Compressive strength MPa
45
Charpy impact strength kJ/m2
3.5-6
Notched izod impact strength kJ/m2
30-50
Hardness Mohs
1
Rockwell hardness R-scale
80-110
Poissons ratio
0.43
Thermal expansion (µm/m)/ºC
80-100
Melt flow rate g/10 min (260 C/2.16 kg)
2-30
Melt temperature ºC
160
Heat deflection temperature ºC
75-130
Thermal conductivity W/mK
0.12
Temperature min-max °C
-10 to 100
Thermal
insulator
Electrical
insulator