Polycarbonate (PC)
3.5-10 usd/kgPolycarbonate (PC) is an important engineering plastic. It offers excellent transparency, toughness, thermal stability and dimensional stability. These properties are utilised in safety-critical applications, such as helmets, visors, lighting and aircraft and ballistic glazing. Its superior moulding characteristics and incredible impact strength make it the go-to material for many automotive, consumer electronic and small appliance housings, too.
The compatibility of PC with other plastics is utilised in alloys (blends), which combine the benefits of the mixed polymers to better fit the performance and productivity requirements of the application. PC is combined with acrylonitrile butadiene styrene (PC/ABS), which is an upgrade on ABS but less expensive than pure PC. It is combined with acrylonitrile styrene acrylate (PC/ASA) for enhanced resistance to weathering and UV light, ensuring colour retention over time. And it is combined with polyester – polyethylene terephthalate (PC/PET) and polybutadiene terephthalate (PC/PBT) – to produce a material with enhanced chemical resistance.
In the past, PC was commonly used in drinks bottles, babies bottles and other food contact applications. Its transparency and impact properties make it a tough and lightweight alternative to glass. However, the downside of PC is its chemistry: it is most commonly formed with the reaction of bisphenol A (produced through the condensation of phenol with acetone under acidic conditions) with carbonyl chloride. Bisphenol A (BPA) has been at the centre of numerous studies, because it poses a risk to people and the environment (it is an endocrine disruptor and oestrogen-mimicker). The concern is that small amounts of the chemicals present in food packaging materials migrate into the contents. The US Food and Drug Administration (FDA) and the European Food Safety Authority (EFSA) consider BPA to be safe at current levels occurring in foods. In other words, they currently approve the use of PC in food containers and packaging (BPA is found in the epoxy-based coatings used to line the inside of metal cans as well as PC). Whether it is dangerous or not, public opinion resulted in a shift away from PC in applications where a ‘safer’ alternative existed.
Sustainability concerns
Polycarbonate (PC) is not commonly available as post-consumer recycled (PCR) material. It is not used in sufficient quantities to justify collection schemes like are used with food packaging polypropylene (PP) and polyethylene terephthalate (PET), polyester. It also tends to be used for longer than typical packaging materials – PC glazing may stay on a roof for 20 years or more. This means the plastic will be quite degraded and its recycling potential reduced. However, it is a valuable material and so will be recycled where possible. Manufacturers are unlikely to waste their offcuts and scrap – these will tend to go straight back into production when using processes like injection moulding. PCR material from automotive and electronics applications, which may not have been exposed to weathering, provide a source of recycled PC (rPC). As long as they are not too contaminated with additives, they can be sorted and melt-processed. rPC is typically used to dilute virgin PC and so reduce its carbon footprint, without negatively impacting performance. Darker colours and non-safety-critical parts can tolerate a higher % of recycled content

