Polycarbonate (PC)

3.5-10 usd/kg
Circularity potential
Low
Strength
Medium
Production energy
Very high
Stiffness
Low
Embodied CO2
High
Density
Medium

Polycarbonate (PC) is an important engineering plastic. It offers excellent transparency, toughness, thermal stability and dimensional stability. These properties are utilised in safety-critical applications, such as helmets, visors, lighting and aircraft and ballistic glazing. Its superior moulding characteristics and incredible impact strength make it the go-to material for many automotive, consumer electronic and small appliance housings, too.

The compatibility of PC with other plastics is utilised in alloys (blends), which combine the benefits of the mixed polymers to better fit the performance and productivity requirements of the application. PC is combined with acrylonitrile butadiene styrene (PC/ABS), which is an upgrade on ABS but less expensive than pure PC. It is combined with acrylonitrile styrene acrylate (PC/ASA) for enhanced resistance to weathering and UV light, ensuring colour retention over time. And it is combined with polyester – polyethylene terephthalate (PC/PET) and polybutadiene terephthalate (PC/PBT) – to produce a material with enhanced chemical resistance.

In the past, PC was commonly used in drinks bottles, babies bottles and other food contact applications. Its transparency and impact properties make it a tough and lightweight alternative to glass. However, the downside of PC is its chemistry: it is most commonly formed with the reaction of bisphenol A (produced through the condensation of phenol with acetone under acidic conditions) with carbonyl chloride. Bisphenol A (BPA) has been at the centre of numerous studies, because it poses a risk to people and the environment (it is an endocrine disruptor and oestrogen-mimicker). The concern is that small amounts of the chemicals present in food packaging materials migrate into the contents. The US Food and Drug Administration (FDA) and the European Food Safety Authority (EFSA) consider BPA to be safe at current levels occurring in foods. In other words, they currently approve the use of PC in food containers and packaging (BPA is found in the epoxy-based coatings used to line the inside of metal cans as well as PC). Whether it is dangerous or not, public opinion resulted in a shift away from PC in applications where a ‘safer’ alternative existed.


Sustainability concerns
Non-renewable ingredients
Raw material generates polluting by-products
Potentially toxic in use
Low circularity potential
Microplastics


High temperature polycarbonate copolymer (PC-HT) retains its mechanical properties to 180 degC or more. This is useful for applications that require the impact performance and clarity of PC, but need to operate at higher temperatures than regular PC is good for, such as spotlights, flashlights, light-guides (transparent moulded parts used to guide light through products and control panels), lenses, reflectors (vacuum metallised), kitchen appliances (dryer and cooker parts, for example), medical products and housings. Like regular PC, it is vulnerable to continuous exposure to warm water, yellowing in UV, and some chemicals and cleaning products. Depending on the grade, transparency is affected by the additive package. This means it is not available in the full colour range of regular PC.


Design properties
Cost usd/kg
4-6
Embodied energy MJ/kg
100-115
Carbon footprint kgCO2e/kg
5-6.5
Density kg/m3
1170
Tensile modulus GPa
2.4-2.6
Tensile strength MPa
71
Flexural modulus GPa
2.5
Flexural strength MPa
110
Charpy impact strength kJ/m2
10
Notched izod impact strength kJ/m2
10
Hardness Mohs
2
Poissons ratio
0.37
Thermal expansion (µm/m)/ºC
65
Melt temperature ºC
310-340
Heat deflection temperature ºC
160
Thermal conductivity W/mK
0.2
Temperature min-max °C
-40 to 150
Thermal
insulator
Electrical
insulator