Natural rubber
2-6 usd/kgNatural rubber is a relatively low cost industrial material produced from the sap of the Pará rubber tree (Hevea brasiliensis). The raw latex is converted into a resilient and high strength material through chemical treatment and vulcanisation (reacted with sulphur at high temperature to harden it). Vulcanisation converts latex into a thermoset material that cannot be melted like thermoplastic elastomers (TPE). The advantage of this is a very durable and resistant material suitable for demanding applications in aerospace, transportation, industrial and manufacturing. The disadvantage is they cannot be recycled into new rubber. Instead, they are ground into crumb, which can be used as a filler material, such as in shock-absorbing floors and insulation. Some types of natural rubber and latex are biodegradable, but in general, they are considered non-biodegradable and take many years to breakdown. Along with synthetic rubber, dust and fragments, such as from tyre wear, contribute to air pollution and as microplastics in food, soil and water.
Natural rubber is resilient with excellent resistance to abrasion, but has poor resistance to oils, petroleum and weathering. Synthetic alternatives have evolved over the years to overcome its shortfalls and include a range of thermoset oil-based rubbers, including silicone and neoprene, as well as thermoplastic types (TPE) that are melt-processible. Even so, natural rubber remains one of the most widely used elastomers, largely due to its low price.
A fully synthetic version of natural rubber exists: polyisoprene (PI). Its consistency, purity and hypoallergenic nature (some people are allergic to the natural proteins in latex), mean it has replaced natural rubber in healthcare and medical items such as gloves, condoms, tubing and needle shields. It is also possible to deproteinise natural rubber to make it safe.
The majority of natural rubber production is not particularly sustainable – it uses harmful chemicals such as ammonia, sodium hydrogen sulphite and formic acid – but as a bio-based plastic, there is potential for it to be renewable and certified (FSC and PEFC for example). In the future, alternative sources may be commercialised that reduce our reliance on a single species of plant. For example, Yulex is scaling up production of certified rubber from the sap of the guayule plant (Parthenium argentatum). Its processes are sustainable and the raw materials are renewable, making this a very exciting development.
Yulex also produce rubber from the Hevea tree using more sustainable techniques – they are certified deforestation-free by PEFC and FSC, and use a water-based purification process – and their materials are biodegradable at the end of their useful life. Considering only around 3% of rubber production worldwide is certified, this is a great achievement.
Sustainability concerns


Natural rubber (NR) is used as a general purpose elastomer in a range of industrial, product, toy, healthcare, medical, automotive, aerospace and transportation applications. It is employed in several formats and the level of vulcanisation determines the mechanical properties. White rubber, referred to as latex or natural rubber latex (NRL), does not contain carbon black and so can be left natural or coloured. It is formed into products as a liquid, such as by coating or dip moulding. Applications include things like gloves, condoms and balloons. As an ingredient in textiles it is used as a waterproof coating (like the famous Mackintosh), bind coir mats (upholstery and floors) and as an inflatable bladder mould, for example.
Crepe rubber is made with coagulated latex that is rolled into naturally crinkled sheets. Known as thick pale crepe (TPC), several sheets are laminated to make material thick enough for the soles of shoes and boots, and also as a raw material for other block rubber products. White crepe that has been bleached is referred to as pale latex crepe (PLC).
Technically specified natural rubber (TSNR) is manufactured according to agreed standards. It is used to make springs, dampers, heavy duty tyres, inner tubes, gaskets and washers. It is typically mixed with additives to improve strength and hardness, as well as blended with synthetic rubbers to improve specific properties. For example, car tyres are typically a mix of natural rubber with butadiene rubber (BR) and styrene butadiene rubber (SBR) along with fillers, additives and fibre reinforcement – car tyre chemistry tends to be a closely guarded secret. The black colour comes from the inclusion of carbon black. This is an important ingredient that enhances the abrasion resistance and tensile strength of rubber, as well as conducting heat and electricity. These qualities are essential for tyres, for example, and is why tyres are black.
Rubber products are formed by compression, injection, extrusion or rotation moulding for example, and vulcanised with sulphur to permanently cross-link the polymer structure. This yields a rubbery material that will always try to spring-back to its moulded shape.