Glass ceramic

8-20 usd/kg
Circularity potential
Ultra low
Strength
High
Production energy
Medium
Stiffness
High
Embodied CO2
Medium
Density
High

Glass ceramic is a family of materials that combines the benefits of both: they are formed like conventional glass (such as pressing, bending and blowing) and crystallised to behave like high performance ceramic. This gives them unique advantages, such as transparency combined with superior thermal shock resistance; or machinability combined with near zero thermal expansion. They are expensive and typically only used for the most demanding applications in aerospace, manufacturing, astronomical telescopes and spacecraft.

These super high performance materials have found their way into our domestic environment as a result of their hard smooth surface, thermal resistance, dielectric strength and dimensional stability. Examples include cookware that can go from freezer to hob, as well as the cooktop itself.

Their unique properties are the result of a parent glass (of which there are many options) and the method of crystallisation. Typically, crystal formation is initiated by a nucleating agent, such as at a specific temperature (heat treatment). This method of forming a polycrystalline material, from a homogenous vitreous parent phase, results in a harmonious crystal structure made up of fine, uniform, randomly orientated interlocking crystals. This near ideal structure yields a material with little or no porosity and optimum mechanical properties. Surface polishing enhances mechanical properties further by reducing imperfections that act as stress concentrators.


Sustainability concerns
Non-renewable ingredients
Raw material generates polluting by-products
Low circularity potential


Lithium aluminosilicate (Li20-Al2O3-SiO2) glass ceramic, also abbreviated as LAS, are a commercial important group of engineering materials made up of lithium oxide (Li2O, 3-6%), aluminium oxide (Al2O3, 18-25%) and silica (SiO2, 58-75%). Originally developed for the mirrors of astronomical telescopes and glass-to-metal seals, they are used to make transparent cooker tops, such as for induction and electric hobs. Similar chemistry is used to make high performance aluminosilicate cover glass for mobile phones, tablets and laptops – without the nucleating agents to convert it into a ceramic – such as Corning Gorilla Glass and Schott Xensation.

This type of glass ceramic is strong, resistant to most chemicals, near zero thermal expansion, and extremely resistant to high temperatures and thermal shock. As a result of wear and tear, and surface defects, practical tensile strength is in the region of 20-200 MPa.

Applications other than cooktops include heater elements, bbq windows and oven doors. Now taken for granted, transparency offers opportunities for design, such as illumination and user-friendly functionality. Examples include Schott Ceran cooktop panels, Robax fireplace windows, Pyran fire resistant glazing and Zerodur precision articles.


Design properties
Compressive strength MPa
750-2129
Hardness Mohs
7.5
Poissons ratio
0.25
Thermal expansion (µm/m)/ºC
0
Thermal
conductive
Electrical
insulator