Epoxy

10-85 usd/kg
Circularity potential
Ultra low
Strength
Medium
Production energy
High
Stiffness
Low
Embodied CO2
High
Density
Medium

Epoxy is a high performance thermosetting resin, which is the product of a one-way chemical reaction. The reaction takes place between a resin and hardener, and is triggered by the mixing process, or as is the case with one-part systems, the reaction is accelerated with heat.

It is a diverse family, including adhesives, coatings, casting resins and laminating resins. On top of this, there are many different types of hardener and a wide range of additive available, which creates the opportunity to tailor the resin to a range of applications. Key properties include high strength, low shrinkage, excellent wet-out and adhesion with other materials, insulating, and resistance to solvents and chemicals.

One downside of epoxy is that it uses some nasty ingredients that are harmful to people and the environment, in particular bisphenol A (BPA) monomer. BPA is a key ingredient of epoxy resin, alongside epichlorohydrin (ECH) – most epoxy systems are derived from reacting these two ingredients. Bisphenol A (BPA) has been at the centre of numerous studies, because it poses a risk to people and the environment (it is an endocrine disruptor and oestrogen-mimicker). The concern is that small amounts of the chemicals present in food packaging materials migrate into the contents.

Even so, certain grades of epoxy are certified as food safe and considered non-toxic by organisations such as the US Food and Drug Administration (FDA) and the European Food Safety Authority (EFSA). As a result, they can be utilised in food contact applications. Examples include coatings on steel water storage tanks and steel food packaging (tin cans), chocolate moulds and table tops.

Another downside is that as a thermosetting resin, it is not recyclable. Bio-based alternatives are emerging that attempt to reduce the negative impacts of this versatile resin by replacing a portion of the petrochemical derived ingredients with potentially renewable ones.


Sustainability concerns
Non-renewable ingredients
Raw material generates polluting by-products
Low circularity potential
Potentially toxic in use


Epoxy is utilised for both functional and decorative castings. Examples include tooling, products, furniture (stand alone castings or combined with other materials, such as encapsulating wood), jewellery and artwork. Tooling is an important industrial application for these materials, including moulds for low-pressure foam moulding (such as used to make upholstery), composite moulds (for prototyping through low volume production), low volume metal stamping (so called soft tooling), and high speed plastic moulding.

Epoxy is cast to shape, CNC machined and polished. It has many advantages, including high strength, dimensional stability, low creep, insulation and high clarity. The resin is mixed with additives and pigments to produce a range of performance and visual effects. It has high resistance to weathering, which can be enhanced with UV-inhibiting additives, to reduce yellowing.

The viscosity and cure cycle are tailored to allow for a range of parts, from small and intricate shapes to thick wall sections, up to 100 mm. The total size and thickness is limited by the exothermic reaction. Very large parts are possible, but may need to be produced in stages, or with a very slow reaction, so the heat given off during curing is manageable and does not damage the mould, or resin itself. Extended cure cycles also help remove air bubbles in large parts.


Design properties
Cost usd/kg
10-15
Embodied energy MJ/kg
76-137
Carbon footprint kgCO2e/kg
8.25
Density kg/m3
1000-1100
Tensile modulus GPa
1.2-4
Tensile strength MPa
30-70
Flexural strength MPa
70-95
Compressive strength MPa
95-120
Hardness Mohs
2.5
Brinell hardness HB
30-40
Poissons ratio
0.35
Thermal conductivity W/mK
0.2
Temperature min-max °C
-40 to 100
Thermal
insulator
Electrical
insulator