Epoxy

10-85 usd/kg
Circularity potential
Ultra low
Strength
Medium
Production energy
High
Stiffness
Low
Embodied CO2
High
Density
Medium

Epoxy is a high performance thermosetting resin, which is the product of a one-way chemical reaction. The reaction takes place between a resin and hardener, and is triggered by the mixing process, or as is the case with one-part systems, the reaction is accelerated with heat.

It is a diverse family, including adhesives, coatings, casting resins and laminating resins. On top of this, there are many different types of hardener and a wide range of additive available, which creates the opportunity to tailor the resin to a range of applications. Key properties include high strength, low shrinkage, excellent wet-out and adhesion with other materials, insulating, and resistance to solvents and chemicals.

One downside of epoxy is that it uses some nasty ingredients that are harmful to people and the environment, in particular bisphenol A (BPA) monomer. BPA is a key ingredient of epoxy resin, alongside epichlorohydrin (ECH) – most epoxy systems are derived from reacting these two ingredients. Bisphenol A (BPA) has been at the centre of numerous studies, because it poses a risk to people and the environment (it is an endocrine disruptor and oestrogen-mimicker). The concern is that small amounts of the chemicals present in food packaging materials migrate into the contents.

Even so, certain grades of epoxy are certified as food safe and considered non-toxic by organisations such as the US Food and Drug Administration (FDA) and the European Food Safety Authority (EFSA). As a result, they can be utilised in food contact applications. Examples include coatings on steel water storage tanks and steel food packaging (tin cans), chocolate moulds and table tops.

Another downside is that as a thermosetting resin, it is not recyclable. Bio-based alternatives are emerging that attempt to reduce the negative impacts of this versatile resin by replacing a portion of the petrochemical derived ingredients with potentially renewable ones.


Sustainability concerns
Non-renewable ingredients
Raw material generates polluting by-products
Low circularity potential
Potentially toxic in use


Polymer concrete (PC) is a composite material reinforced with aggregate and sometimes powder and fibre – the Portland cement is partially (>5%) or wholly replaced with polymer. Instead of cement binding the aggregate, it is held together by the polymer matrix, which forms a very strong bond. Suitable polymers include polyester resin, epoxy, vinyl ester, acrylic and many others, both thermoset (form permanent cross-links) and thermoplastic (soften when heated). Choice depends on the requirements of the applications, such as whether it will be exposed to weathering, sunlight and temperature extremes. For example, epoxy has the best mechanical properties, polyester is the least expensive and acrylic has good resistance to weathering. Aggregates and fibres (AR-glass and carbon for example) reinforce the polymer matrix, and as with any composite, greatly influence mechanical properties.

A major advantage of PC is, unlike Portand cement concrete, there are no voids left once curing is complete. Regular concrete is very cost-effective, but it suffers from low strength and flexural properties, which are exasperated by its poor resistance to water penetration, freeze-thaw phenomena and acids. Additional advantages of PC include rapid curing, mechanical properties, resistance to chemicals and corrosion, and good moulding properties. It also bonds very well to steel, and other materials used in structural applications – much better than cement.

Applications include pavements, pipelines, bridges, dams and floors. It is also used extensively as a repair material. Precast PC is used in the production of tanks (such as for acids), paving, manhole covers, drains and barriers, for example.


Design properties
Cost usd/kg
2.5-7.5
Embodied energy MJ/kg
23-41
Carbon footprint kgCO2e/kg
1.5-2.5
Density kg/m3
1900-2800
Tensile modulus GPa
25-35
Tensile strength MPa
25-40
Flexural strength MPa
4.5-40
Compressive strength MPa
37-120
Hardness Mohs
4
Poissons ratio
0.2
Thermal expansion (µm/m)/ºC
12.5-28.6
Temperature min-max °C
-40 to 100
Thermal
insulator
Electrical
insulator